highlighting active leaching of hydrocarbons from the unsaturated zone into the aquifer. The strong correlation
between soil and groundwater TPH (r = 0.86; R² = 0.74) confirms that approximately 74 % of groundwater
contamination variability can be attributed to soil hydrocarbon load. This agrees with Akpan and Udosen
(2018) and Nwankwoala and Osibanjo (2020), who documented strong soil–groundwater coupling around
petrol stations in southern Nigeria. Comparable linkages have also been reported in Egypt (El Alfy et al., 2022)
and India (Kumar et al., 2021), underscoring that subsurface hydrocarbon migration is a global challenge,
particularly in sandy, highpermeability terrains. Benzene concentrations in groundwater (up to 0.034 mg/L at
NT-06) further affirm soil–water interaction, with a correlation coefficient of r = 0.74 suggesting capillary
diffusion or vapor-phase migration through the vadose zone. Adelana et al. (2019) and Rahman et al. (2022)
similarly reported persistent benzene pollution in groundwater beneath petroleum facilities, highlighting its
carcinogenic potential even at low concentrations.
Moderate correlations between soil and groundwater Pb (r = 0.59) and Ni (r = 0.67) also indicate partial metal
leaching influenced by acidic pH and local hydrodynamics. According to Ololade et al. (2019) and Eze and
Nwaogazie (2021), acidic and reducing conditions enhance metal desorption from soil particles, increasing
their mobility in shallow aquifers. The regression model for Ni (R² = 0.45) further confirms moderate soil-to-
groundwater transfer efficiency, consistent with Ibe and Uzoigwe (2020), who found seasonal enhancement of
metal migration near aged fuel stations in southeastern Nigeria. The prevailing groundwater flow direction
(120°–172° SE) suggests plume migration toward the southeast, consistent with local topography and slope
patterns. Ekanem et al. (2022) identified similar plume alignment in contiguous LGAs, indicating hydrological
continuity across the region. The integrated Geo-Environmental Risk Matrix classified the six study sites into
moderate to very high-risk categories, with Nto Eton emerging as the most critical hotspot due to high TPH in
both soil and groundwater, shallow water table (5.9 m), and multiple exceedances across parameters. The
combined PLI (0.93–1.79 for soil; 1.56–2.15 for water) mirrors values reported by Udo et al. (2020) for Uyo
Metropolis, suggesting co-contamination by hydrocarbons and metals. Overall, contamination pathways are
governed by leakage from corroded storage tanks, infiltration through sandy loam soils, and absence of post-
decommissioning remediation a pattern consistent with those described globally by Al-Bassam and Naji (2021)
and Akinbile et al. (2022).
Although this study analyzed six representative abandoned petrol stations strategically distributed across
Essien Udim, logistical constraints limited broader spatial sampling. The number of sites, while representative
of distinct hydrogeological and operational settings, may not capture microscale variability. Seasonal
fluctuations in contaminant concentrations and potential analytical uncertainties could also influence measured
values. Nevertheless, the strong soilwater correlations and consistency with comparable national and global
data validate the reliability of these findings. Future research should include seasonal monitoring, isotopic
tracing, and geostatistical modeling to refine plume prediction and long-term risk assessment.
CONCLUSION
The study demonstrates that abandoned petrol stations in Essien Udim Local Government Area pose serious
environmental risks to both soil and groundwater systems. Elevated TPH, benzene, Pb, and Ni levels surpass
recommended safety thresholds, with strong positive correlations between soil and groundwater contamination.
Acidic soil conditions promote metal solubility and hydrocarbon mobility, facilitating downward migration
into aquifers. Groundwater flow analysis indicates southeastward contaminant plume movement, increasing
the vulnerability of shallow wells in adjacent communities. These findings corroborate national (Ekanem et al.,
2022; Adekola et al., 2020) and international (Kumar et al., 2021; Rahman et al., 2022) studies, emphasizing
that abandoned fuel facilities remain long-term sources of subsurface contamination. Without immediate
remediation, continued hydrocarbon seepage will exacerbate soil degradation, disrupt microbial processes, and
compromise groundwater safety. Consequently, the study recommends a comprehensive riskbased
management framework, incorporating soil washing, phytoremediation, and regular groundwater monitoring in
compliance with DPR and WHO standards.
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