Conversion of Anthropogenic CO₂ and Waste Flue Dust from Cement Factories into Calcium Carbonate and Magnesium Carbonate: A Circular Approach to Carbon Mitigation

Authors

Ahmad, A.

Department of Applied Chemistry, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria (Nigeria)

Isah, A.

Department of Applied Chemistry, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria (Nigeria)

Zaki, U. F.

Department of Energy and Applied Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria (Nigeria)

Bello, B. A.

Department of Applied Chemistry, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria (Nigeria)

Wakkala, A.

Department of Applied Chemistry, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria (Nigeria)

Barau, H.

Department of Applied Biology, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria (Nigeria)

Yusuf, T.

State College of Basic and Remedial Studies, Sokoto (Nigeria)

Article Information

DOI: 10.51584/IJRIAS.2026.11060033

Subject Category: Chemistry

Volume/Issue: 11/6 | Page No: 326-335

Publication Timeline

Submitted: 2026-05-21

Accepted: 2026-05-26

Published: 2026-06-19

Abstract

Industrial flue dust, an abundant byproduct of metallurgical processes, was evaluated as a low-cost CO₂ material for CO2 conversion to calcium carbonate and magnesium carbonate under ambient conditions. Batch system experiments compared CO₂ concentration profiles in a sealed chamber with and without flue dust at 25 °C and 1 atm., using a CO₂ injection rate of 20 mL per 30 s. In the absence of flue dust, CO₂ concentration rose steadily from 407–414 ppm to 1058 ppm at 900 s, reflecting passive accumulation. With flue dust present, CO₂ levels remained near ambient for up to 690 s, with measured concentrations 124–286 ppm lower than the control during 240–690 s. This corresponds to a CO₂ removal capacity of 23.5–41.4%, peaking at 41.4% before declining to 3.5% at 900 s due to reduction of calcium and magnesium oxide.

Keywords

Anthropogenic CO₂, Flue Dust, Carbonation, Climate change

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