Conversion of Anthropogenic CO₂ and Waste Flue Dust from Cement Factories into Calcium Carbonate and Magnesium Carbonate: A Circular Approach to Carbon Mitigation
Authors
Department of Applied Chemistry, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria (Nigeria)
Department of Applied Chemistry, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria (Nigeria)
Department of Energy and Applied Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria (Nigeria)
Department of Applied Chemistry, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria (Nigeria)
Department of Applied Chemistry, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria (Nigeria)
Department of Applied Biology, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria (Nigeria)
State College of Basic and Remedial Studies, Sokoto (Nigeria)
Article Information
DOI: 10.51584/IJRIAS.2026.11060033
Subject Category: Chemistry
Volume/Issue: 11/6 | Page No: 326-335
Publication Timeline
Submitted: 2026-05-21
Accepted: 2026-05-26
Published: 2026-06-19
Abstract
Industrial flue dust, an abundant byproduct of metallurgical processes, was evaluated as a low-cost CO₂ material for CO2 conversion to calcium carbonate and magnesium carbonate under ambient conditions. Batch system experiments compared CO₂ concentration profiles in a sealed chamber with and without flue dust at 25 °C and 1 atm., using a CO₂ injection rate of 20 mL per 30 s. In the absence of flue dust, CO₂ concentration rose steadily from 407–414 ppm to 1058 ppm at 900 s, reflecting passive accumulation. With flue dust present, CO₂ levels remained near ambient for up to 690 s, with measured concentrations 124–286 ppm lower than the control during 240–690 s. This corresponds to a CO₂ removal capacity of 23.5–41.4%, peaking at 41.4% before declining to 3.5% at 900 s due to reduction of calcium and magnesium oxide.
Keywords
Anthropogenic CO₂, Flue Dust, Carbonation, Climate change
Downloads
References
1. Adewole, T. A., Adejugbe, O. A., and Okediran, I. O. (2024). Sustainable construction and the environmental impact of cement production in Nigeria. Nigerian Journal of Environmental Sciences and Technology, 8(1), 112-125. [Google Scholar] [Crossref]
2. Alam, M., Akbar, A., Farooq, F., & Javed, M. F. (2024). Carbon sequestration potential of cement kiln dust: Mechanisms, methodologies, and applications. _Journal of CO₂ Utilization, 82_, 102734.https://doi.org/10.1016/j.jcou.2024.102734 [Google Scholar] [Crossref]
3. Al-Bayati, H. K., Fall, M., & Benzaazoua, M. (2024). Experimental investigation of recycling cement kiln dust in cemented paste backfill. Minerals,14(3),267.https://doi.org/10.3390/min14030267 [Google Scholar] [Crossref]
4. Al-Salloum, Y. A., Abbas, H., Almusallam, T. H., & Alhozaimy, A. M. (2023). Cement kiln dust (CKD) as a partial substitute for cement in pozzolanic concrete blocks. Materials, 16(5), 1923. https://doi.org/10.3390/ma16051923 [Google Scholar] [Crossref]
5. Audu, M. T., Osinubi, K. J., and Ekanem, A. M. (2023). Cement kiln dust for CO₂ sequestration in Nigeria. Journal of Cleaner Production, 402, 136815. https://doi.org/10.1016/j.jclepro.2023.136815 [Google Scholar] [Crossref]
6. Bartoli, M., Molino, A., & Mezzetta, A. (2023). Accelerated direct carbonation of steel slag and cement kiln dust: An industrial symbiosis strategy applied in the Bergamo–Brescia area. _Materials, 16_(12),4321.https://doi.org/10.3390/ma16124321 [Google Scholar] [Crossref]
7. Bashir, F. M. (2023). Industrial emissions and public health in Northwestern Nigeria: A review. Sokoto Journal of Public Health, 4(2), 45-58. [Google Scholar] [Crossref]
8. Benhelal, E., Shamsaei, E., & Rashid, M. I. (2021). Challenges against CO2 emissions in the cement industry. Journal of Cleaner Production, 312, 127666. https://doi.org/10.1016/j.jclepro.2021.127666 [Google Scholar] [Crossref]
9. BUA Cement Plc. (2023). Annual Report and Financial Statements 2022. Retrieved January 21, 2026, from https://www.buacement.com [Google Scholar] [Crossref]
10. Dangote Cement Plc. (2023). Annual Report 2022. Retrieved January 21, 2026, from https://www.dangotecement.com [Google Scholar] [Crossref]
11. Ellen MacArthur Foundation. (2020). What is a circular economy? Retrieved January 21, 2026, from https://www.ellenmacarthurfoundation.org/circular-economy/what-is-the-circular-economy [Google Scholar] [Crossref]
12. El-Nagar, D., El-Naggar, A. M., & Aboelenin, A. (2019). Optimization of bio-cement production from cement kiln dust using microalgae. Scientific Reports,9,19856.https://doi.org/10.1038/s41598-019-56342-3 [Google Scholar] [Crossref]
13. Federal Government of Nigeria. (2022). Nigeria Energy Transition Plan. Federal Ministry of Environment. [Google Scholar] [Crossref]
14. Federal Ministry of Environment. (2021). Nigeria's Nationally Determined Contributions (NDCs). Retrieved January 21, 2026, from https://www.unfccc.int/sites/ndcstaging/ PublishedDocuments/Nigeria%20First/NIGERIA%20UPDATED%20NDC%20DOCUMENT.pdf [Google Scholar] [Crossref]
15. Global Cement and Concrete Association (GCCA). (2023). Our Roadmap to Net Zero Concrete. Retrieved January 21, 2026, from https://gccassociation.org/our-work/sustainability/our-roadmap-to-net-zero-concrete/ [Google Scholar] [Crossref]
16. Grim, R. G., Huang, Z., Guarnieri, M. T., and Fermi, A. (2020). Global fuel combustion CO₂ emissions. Environmental Science and Technology, 54(19), 11234–11243. [Google Scholar] [Crossref]
17. Ibrahim, A., and Aliyu, J. (2022). Desertification and land use in Northwestern Nigeria: A review. Journal of Arid Environments, 195, 104876. [Google Scholar] [Crossref]
18. International Energy Agency (IEA). (2022). Cement Technology Roadmap. Retrieved January 21, 2026, from https://www.iea.org/reports/cement [Google Scholar] [Crossref]
19. Isah, A. (2022). CO₂ hydrogenation to methane over Zeolite promoted Ni/CO₂ Catalysts at Atmospheric Pressure. International Journal of Applied Science Research and Review, 9, 101. [Google Scholar] [Crossref]
20. Isah, A., Akanyeti, I., and Oladipo, A. A. (2020). Methanation of CO₂ over zeolite-promoted Ni/Al₂O₃ nanocatalyst under atmospheric pressure. Reaction Kinetics, Mechanisms and Catalysis, 130, 167–183. https://doi.org/10.1007/s11144-020-01782-z [Google Scholar] [Crossref]
21. National Bureau of Statistics (NBS). (2023). Industrial Sector Report Q4 2022. Retrieved January 21, 2026, from https://www.nigerianstat.gov.ng [Google Scholar] [Crossref]
22. Ndefo, O. (2021). Health risk and environmental assessment of cement production in Nigeria. International Journal of Environmental Research and Public Health, 18(16), 8567. https://doi.org/10.3390/ijerph18168567 [Google Scholar] [Crossref]
23. Nigeria Extractive Industries Transparency Initiative (NEITI). (2023). Solid Minerals Industry Report 2021. Retrieved January 21, 2026, from https://www.neiti.gov.ng [Google Scholar] [Crossref]
24. Nuhu, A. D., Ojo, O. T., and Salami, L. (2022). Heavy metal immobilization in carbonated CKD. Science of the Total Environment, 807, 150774. [Google Scholar] [Crossref]
25. Oyedepo, S. O. (2021). Sustainable waste management in Nigerian cement plants. Resources Policy, 74, 102321. https://doi.org/10.1016/j.resourpol.2021.102321 [Google Scholar] [Crossref]
26. Pan, S. Y., Ling, T. C., and Park, A. A. (2023). Mineral carbonation of industrial wastes. Environmental Science and. F., Muhammad, D. F., Muhammad, K. H., Adamu, S. S., Kabir, M. B., and Bello, B. A. (2025). Potential of activated charcoal and aniline-modified charcoal in carbon dioxide capture. [Google Scholar] [Crossref]
27. Sanna, A., Dri, M., and Hall, M. R. (2022). CKD-based carbon capture in the USA. International Journal of Greenhouse Gas Control, 113, 103532. [Google Scholar] [Crossref]
28. Shehu, A. (2022). Impact of industrial waste on groundwater quality in Kalambaina, Sokoto State. Nigerian Journal of Environmental Sciences, 10(2), 45-58. [Google Scholar] [Crossref]
29. Shen, Y., Zhang, Y., and Chen, G. (2020). Enhanced CO₂ adsorption on modified activated carbon. Journal of Environmental Sciences, 90, 120–128. [Google Scholar] [Crossref]
30. Song, J., Shen, J., and Li, Y. (2020). CO₂ adsorption on activated carbons: A review. Journal of Environmental Sciences, 90, 1–13. [Google Scholar] [Crossref]
31. Streck, C., Keenlyside, P., and Unger, M. (2022). The Paris Agreement and the global climate change regime. Climate Policy, 22(5), 631–642. [Google Scholar] [Crossref]
32. UNIDO. (2020). Industrial Development Report 2020: Industrializing in the digital age. United Nations Industrial Development Organization. [Google Scholar] [Crossref]
33. World Bank. (2023). State and Trends of Carbon Pricing 2023. World Bank Group. Retrieved January 21, 2026, from https://www.worldbank.org/en/programs/pricing-carbon [Google Scholar] [Crossref]
34. World Commission on Environment and Development (WCED). (1987). Our Common Future. Oxford University Press. [Google Scholar] [Crossref]
35. Zhang, N., Li, H., and Liu, X. (2023). Activation mechanisms of cement kiln dust. Chemical Engineering Journal, 451, 138522. https://doi.org/10.1016/j.cej.2022.138522 [Google Scholar] [Crossref]
36. Sanusi, I. M., Isah, A., Zaki, U. F., Muhammad, D. F., Muhammad, K. H., Adamu, S. S., (2025). Potential of Activated Charcoal and Aniline-Modified Charcoal in [Google Scholar] [Crossref]
37. Carbon Dioxide Capture , Nigerian Research Journal of Chemical Sciences (ISSN: 2682-6054)Volume 13, Issue 2, 2025 [Google Scholar] [Crossref]
Metrics
Views & Downloads
Similar Articles
- Green Synthesis of Cobalt Oxide/Gold (Coo/Au) Bimetallic Nanoparticles Using Sinapinic Acid: A Comprehensive Study
- Advances in Solar Cell Technologies: A Comprehensive Review of Material Synthesis, Structural Properties, Efficiency and Diverse Applications
- Thermal Decomposition of Co-Fe-Cr-Citrate Complex Via Structural and Spectral Study
- Surface Activity and Thermodynamic Assessment of Surfactants Derived from Oreochromis Niloticus Oil (Nile Tilapia Fish)
- Green Synthesis of Robust Metal-Organic Frameworks: A Sustainable Approach for Advanced Applications