Investigation of the Effects of Hybrid Agro Waste-Fillers on the Properties of Flexible Polyurethane Foams for Nursery Farming Applications

Authors

Okeke, O.J

Department of Pure and Industrial Chemistry, Faculty of Physical Science, Nnamdi Azikwe University, Awka, Anambra State (Nigeria)

Chris-Okafor P.U

Department of Pure and Industrial Chemistry, Faculty of Physical Science, Nnamdi Azikwe University, Awka, Anambra State (Nigeria)

Anarado, C.E

Department of Pure and Industrial Chemistry, Faculty of Physical Science, Nnamdi Azikwe University, Awka, Anambra State (Nigeria)

Article Information

DOI: 10.51584/IJRIAS.2026.110200170

Subject Category: Chemistry

Volume/Issue: 11/2 | Page No: 1819-1830

Publication Timeline

Submitted: 2026-02-24

Accepted: 2026-03-03

Published: 2026-03-24

Abstract

The use of agro-waste materials as fillers in polymer composites offers a sustainable route to reducing environmental impact and production cost while enhancing material performance. This study investigates the influence of guinea corn husk/snail shell hybrid filler on the physical, mechanical, morphological, and biodegradability properties of flexible polyurethane foam intended for nursery farming applications. The hybrid filler, composed of equal proportions of lignocellulosic guinea corn husk and calcium-carbonate-rich snail shell, was incorporated at 0–25 wt%. Results showed that increasing filler loading prolonged foaming reactions and increased density, with rise time increasing from 145 s to 166 s, cure time from 7.5 to 8.8 min, and apparent density from 28.4 to 32.2 kg/m³. Mechanical performance improved progressively, as tensile strength, flexural strength, compressive strength, and hardness increased with filler content, while strain at break decreased, indicating enhanced stiffness but reduced ductility. Scanning electron microscopy revealed a transformation from large, irregular cells in the control foam to smaller, more uniform cells with thicker walls in filled samples. Soil burial testing confirmed the biodegradable nature of the composite material. Overall, the guinea corn husk/snail shell hybrid filler significantly improved structural integrity and load-bearing capacity while maintaining environmental compatibility, demonstrating strong potential for cushioning, root protection, and seedling support in nursery farming systems.

Keywords

Flexible polyurethane foam; Guinea corn husk; Snail shell; Agro-waste composites; Nursery farming applications

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References

1. Acosta, A. P., Otoni, C. G., Missio, A. L., Amico, S. C. and Delucis, R. Á. (2022). Rigid Polyurethane Biofoams Filled with Chemically Compatible Fruit Peels. Polymers, 14(21), 4526. [Google Scholar] [Crossref]

2. Aidoo, O. B., Agyei-Tuffour, B., Essuman, E. and Oteng-Darko, P. (2025). Thermomechanical properties of sustainable polymer composites with agricultural waste fillers. Technologies, 13(9), 315. [Google Scholar] [Crossref]

3. Bartczak, P., Szylińczuk, K., Tomaszczak, M. and Borysiak S. (2024). Sustainable and multifunctional polyurethane green composites with renewable materials. Journal of Materials Science, 59(30), 13541–13557. [Google Scholar] [Crossref]

4. Bheel, N. D. and Mangi, S. A. (2021). Coconut Shell Ash as Cementitious Material in Concrete: A Review. Jurnal Kejuruteraan, 33(1), 27–38. [Google Scholar] [Crossref]

5. Caschera, A., Calayan, T., Piccolo, N., Kakroodi A., Robinson, J. J. and Sacripante G. (2024). Degradation of bioderived polyurethane composites by spectroscopy in ISO20200 composting conditions. Polymers, 16(14), 2071. [Google Scholar] [Crossref]

6. Chen, M., Yuan, Y., Wang, W., and Xu, L. (2025). Recent advances in flame retardant flexible polyurethane foams. Fire, 8(3), 90. [Google Scholar] [Crossref]

7. Cheng, Y., Wang, J. and Li, H. (2019). Thermal and mechanical properties of bio-filler polyurethane composites. Industrial Crops and Products, 134, 44–52. [Google Scholar] [Crossref]

8. Ching Y. C., Ho C. S., and Abdullah L. C. (2018). Natural fiber-reinforced polyurethane foams: Structure–property relationships. Journal of Applied Polymer Science, 135(29), 46470. [Google Scholar] [Crossref]

9. Ching, C. K., Lee, S. H. and Lim, T. C. (2018). Effects of lignocellulosic fillers on polyurethane foam performance. Journal of Applied Polymer Science, 135(12), 45921. [Google Scholar] [Crossref]

10. Das, S., Gupta, R. and Banerjee, A. (2020). Rice straw incorporation in PU foam composites. Journal of Applied Polymer Science, 137(18), 48562. [Google Scholar] [Crossref]

11. Dutta, S., Chowdhury, A. and Saha P. (2021). Polyurethane hybrid composites: A comprehensive review of structure, morphology, and reinforcement performance. Progress in Polymer Science, 118, 101425. [Google Scholar] [Crossref]

12. Dutta, S., Sarkar, B. and Roy, P. (2021). Influence of natural fillers on polyurethane foam cure kinetics and mechanical properties. Polymer Testing, 99, 107150. [Google Scholar] [Crossref]

13. El Metwaly, E. A., Mohamed H. E., El Basheer T. M., Moselhy M. T. H., Zulfiqar S., Cochran E. W. and Maamoun A. A. (2024). Eco conscious upcycling of sugarcane bagasse into flexible polyurethane foam for mechanical & acoustic relevance. RSC Advances, 14, 23683–23692. [Google Scholar] [Crossref]

14. El-Sayed, M. (2020). Biodegradability of biofilled polyurethane foams under soil burial conditions. Journal of Polymer and the Environment, 28(8), 2345–2358. [Google Scholar] [Crossref]

15. Fernandes S., Moreira P. and Domingues V. (2022). Cell morphology evolution in mineral-filled polyurethane foams: Effects on mechanical and thermal properties. Materials Today Communications, 33, 104521. [Google Scholar] [Crossref]

16. Fernandes, M., Soares, B. and Costa, H. (2022). Mineral-organic hybrid fillers in flexible polyurethane foams: Effects on physical and mechanical performance. Composites Part B: Engineering, 235, 109789. [Google Scholar] [Crossref]

17. Gama, N., Silva, R. and Ferreira, A. (2018). Sustainable polyurethane foams reinforced with lignocellulosic fibers. Journal of Cleaner Production, 187, 28–40. [Google Scholar] [Crossref]

18. Głowacz Czerwonka, D., Zakrzewska, P., Oleksy, M., Pielichowska, K. and Kuźnia, M. (2023). The influence of biowaste based fillers on the mechanical and fire properties of rigid polyurethane foams. Sustainable Materials and Technologies, 36, e00610. [Google Scholar] [Crossref]

19. Greco, A., Morelli, M. and Di Maio, L. (2021). Natural fiber and CaCO₃ reinforced polyurethane foams: Structural and mechanical insights. Journal of Materials Research and Technology, 14, 1567–1579. [Google Scholar] [Crossref]

20. John, M. J. and Thomas, S. (2018). Green composites from agricultural residues. Carbohydrate Polymers, 207, 530–540. [Google Scholar] [Crossref]

21. Khazabi, M., Rashidi, A. and Farhadi, M. (2011). Lignocellulosic filler effects on microstructure and properties of polyurethane foams. Cellulose Chemistry and Technology, 45(9–10), 631–640. [Google Scholar] [Crossref]

22. Kim, S., Park, J. and Lee, K. (2021). Cell morphology of PU foams with natural fillers. Polymer Composites, 42(11), 5872–5885. [Google Scholar] [Crossref]

23. Lee D. I., Ha Y. H., Jeon H. and Kim S. H. (2022) Preparation and Properties of Polyurethane Composite Foams with Silica-Based Fillers. Applied Sciences, 12(15), 7418. [Google Scholar] [Crossref]

24. Lee, S. H. and Bae, C. M. (2023). Understanding the flame retardant mechanism of intumescent flame retardant on improving the fire safety of rigid polyurethane foam. Polymers, 14(22), 4904. [Google Scholar] [Crossref]

25. Leszczyńska M., Ryszkowska J. and Szczepkowski L. (2020). Rigid polyurethane foam composites with nut shells. Polimery, 65(10), 728–737. [Google Scholar] [Crossref]

26. Li H., Zhang Y., Wang X. and Chen L. (2022) Mechanical and thermal performance of polyurethane foams reinforced with wheat straw fibers. Composites Part B: Engineering, 242, 110038. [Google Scholar] [Crossref]

27. Li, H., Mokale Kognou, A. L., Jiang, Z.-H., Qin, W., & Xu, C. C. (2022). Production of bio polyurethane (BPU) foams from greenhouse/agricultural wastes, and their biodegradability. Biofuels, Bioproducts and Biorefining, 16(6), 1894–1908. [Google Scholar] [Crossref]

28. Liu, Y., Chen, F. and Huang, Y. (2020). Bio- and mineral-filled polyurethane foams: Morphology, mechanical, and density analysis. Journal of Cellular Plastics, 56(5), 457–474. [Google Scholar] [Crossref]

29. Lubczak R, Kus Liśkiewicz M, Lubczak J, Szpiłyk M, Broda D and Bobko E (2024) Biodegradable Polyurethane Foams Based on Polyols Obtained from Cellulose and Its Hydroxypropyl Derivative. Materials, 17(22), 5490. [Google Scholar] [Crossref]

30. Onwuka, C. O., Anekwe, O. J., Ogudo, M. C., Chris Okafor, P. U. (2021). Impact of mixed fillers on the physico mechanical properties of flexible polyether foam. Organic Polymer Material Research, 3(1) [Google Scholar] [Crossref]

31. Onyenweaku, C. E., Nwokoye, J. N., Chris Okafor, P. U. (2021). Mechanical and surface morphology properties of low-density polyethylene composites filled with organic materials. American Journal of Mechanical and Materials Engineering, 5(1), 1–4 [Google Scholar] [Crossref]

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