Soils Quality Assessment in Kambele Gold Mining Area using Multivariate Statistical Analysis Approach
Authors
School of Geology and Mining Engineering, University of Ngaoundéré, P.O. Box 115, Meiganga, Cameroon. (Cameroon)
Department of Geography, Faculty of arts, letter and social science, University of Yaoundé 1, Cameroon. (Cameroon)
School of Geology and Mining Engineering, University of Ngaoundéré, P.O. Box 115, Meiganga, Cameroon. (Cameroon)
School of Geology and Mining Engineering, University of Ngaoundéré, P.O. Box 115, Meiganga, Cameroon. (Cameroon)
Department of Geography, Faculty of arts, letter and social science, University of Yaoundé 1, Cameroon. (Cameroon)
School of Geology and Mining Engineering, University of Ngaoundéré, P.O. Box 115, Meiganga, Cameroon.\Laboratory of Mechanics and Materials of Civil Engineering (L2MGC), CY Cergy Paris University, 5 Mail Gay Lussac, Neuville sur Oise, F-95031 Cergy-Pontoise Cedex, France. (Cameroon\ France)
Article Information
DOI: 10.51244/IJRSI.2026.1306000175
Subject Category: Environment
Volume/Issue: 13/6 | Page No: 2367-2409
Publication Timeline
Submitted: 2026-04-13
Accepted: 2026-04-18
Published: 2026-06-29
Abstract
This study assesses soil quality in the Kambele gold mining area (Eastern Cameroon) through integrated physico-chemical characterization, pollution index calculation, multivariate statistical analysis, and spatial mapping. Thirty surface soil samples (0-5 cm depth) were collected in June 2021 using systematic random sampling across the 30 km² study area. Physico-chemical parameters (pH, electrical conductivity, organic matter, moisture content) and heavy metal concentrations (Cr, Ni, Cu, Zn, Pb, Fe, Mn, As) were determined using XRF spectrometry (Skyray EDX POCKET III). Results reveal acidic soils (pH 5.12-6.22) with elevated electrical conductivity (96-416 μS/cm) and variable organic matter (0.30-1.42%). Heavy metal concentrations show significant contamination exceeding WHO guidelines for Pb (max 114 ppm), Cu (485 ppm), Ni (655 ppm), As (60 ppm), and Fe (121,611 ppm). Comprehensive pollution assessment using 15 indices (EF, Igeo, CF, PI, PLI, PIVector, MEC, CSI, Cdeg, Nemerow, Potential Ecological Risk, ExF, mCd) indicates moderate to extreme contamination, with Cu and Ni showing the highest enrichment. Principal Component Analysis (PCA) explains 72.83% of total variance, identifying three contamination sources : natural pedogeochemical background (PC1 : 49.93%), mining-related inputs (PC2: 22.90%), and mixed anthropogenic sources (PC3: 12.07%). Spatial kriging maps reveal heterogeneous contamination patterns with identified hotspots at Djengou washing station (E28) and site E8. Human health risk assessment indicates non-carcinogenic hazard indices exceeding USEPA thresholds for children (HI > 1) at multiple locations, primarily driven by As, Pb, and Cu exposure. These findings underscore the urgent need for targeted remediation strategies, including phytoremediation for moderately contaminated areas, soil amendments for pH adjustment, and containment measures for severe hotspots. This study provides the first comprehensive environmental baseline for Kambele, supporting evidence-based policy interventions and community health protection measures.
Keywords
Mining exploitation, soils, contamination, pollution, heavy metals, health risk assessment, spatial analysis
Downloads
References
1. Abdullateef, J., Agbaji1, E.B., Ajibola1, V.O., Funtua, M.A., (2020). Application of Pollution Load Indices, Enrichment Factors,Contamination Factor and Health Risk Assessment of soils. Open J Anal Bioanal Chem. 4(1), 011-019. [Google Scholar] [Crossref]
2. Abhijit, M., Maiti, R., (2018). Geochemical contamination in the mine affected soil of Raniganj Coalfield–A river basin scale assessment. Geoscience Frontiers, 9(5), 1577-1590. [Google Scholar] [Crossref]
3. Abrahim, G.M.S., Parker, R. J., ( 2008). Assessment of heavy metal enrichment factors and the degree of contamination in marine sediments from Tamaki Estuary, Auckland, New Zealand. Environmental Monitoring and Assessment. 136, 227–238. [Google Scholar] [Crossref]
4. Adamu, C.I., Nganje, T.N., (2010). Heavy metal contamination of surface soil in relationship to land use patterns: A case study of Benue State, Nigeria. Materials Sciences and Applications. 1, 127–134. [Google Scholar] [Crossref]
5. Adenuga, A.A., Olufemi, D.A., Olajide, O.D., Eludoyin, A.O., Idowu, O.O., (2022). Environmental impact and health risk assessment of potentially toxic metals emanating from different anthropogenic activities related to E-wastes. Heliyon. 8(8), e10296. [Google Scholar] [Crossref]
6. Affum, A.O., Osae, S.D., Kwaansa-Ansah, E.E., Miyittah, M.K., (2020). Quality assessment and potential health risk of heavy metals in leafy and non-leafy vegetables irrigated with groundwater and municipal-waste-dominated stream in the Western Region, Ghana. Heliyon. Volume 6 (12), e05829. [Google Scholar] [Crossref]
7. Awasthi, G., Nagar, V., K.K., Rajput, V., Bauer, T., Srivastava, S., (2022). Sustainable Amelioration of Heavy Metals in Soil Ecosystem:Existing Developments to Emerging Trends. Minerals. 12, 85. [Google Scholar] [Crossref]
8. Axtmann, E.V., Luoma, S.N., (1991). Large-Scale Distribution of Metal Contamination in the Fine-Grained Sediments of the Clark Fork River, Montana, U.S.A. Applied Geochemistry . 6, 75-88. [Google Scholar] [Crossref]
9. Ayiwouo, M.N., Mambou, L.L.N., Takougang, S.K., Ngounouno, I., (2022). Spatio‑temporal variation and assessment of trace metal contamination in sediments along the Lom River in the gold mining site of Gankombol (Adamawa Cameroon). Environmental Earth Sciences. 81(379), 1-20. [Google Scholar] [Crossref]
10. Babelewska, A., (2010). The impact of industrial emissions on heavy metal and sulphur contamination level within the area of the projected Jurassic National Park. Pra˛dnik Studies and Reports of the Prof Władysław Szafer Museum. 20, 135–145. [Google Scholar] [Crossref]
11. Baby, J., Raj, J.S., Biby, E.T., Sankarganesh, P., Jeevitha, M.V., Ajisha, S.U., Rajan, S.S., (2010). Toxic effect of heavy metals on aquatic environment. Int. J. Biol. Chem. Sci. 4, 939-952. [Google Scholar] [Crossref]
12. Bade, R., Oh, S., Shin, W., Hwang, I., (2013,). Human health risk assessment of soils contaminated with tal(loid)s by using DGT uptake: A case study of a former Korean metal refinery site. Hum.Ecol. Risk Assessment , 19, 767–777. [Google Scholar] [Crossref]
13. Baird, C., Michael, C., (2012). Environmental chemistry. Fifth Edition. Macmillan Higher Education. [Google Scholar] [Crossref]
14. Baker, D.E., Alloway, B.J., (2000). Analysis of heavy metals in soil. Int. J. Agric. Policy Res. 1(2), 151-196. [Google Scholar] [Crossref]
15. Bhargava, A., Carmona, F.F., Bhargava, M., Srivastava, S., (2012.). Approachesforenhanced phytoextractionofheavymetals. J.Environ.Manage. 105,103–120. [Google Scholar] [Crossref]
16. Banunle, A., Fei-Baffoe, B., Otchere, K.G., (2018). Determination of the Physico-Chemical Properties and Heavy Metal Status of the Tano River along the Catchment of the Ahafo Mine in the Brong-Ahafo Mine. Ghana. J Environ Anal Toxicol. 8(3), 2-11. [Google Scholar] [Crossref]
17. Brady D, Duncan J.R., (1994). Bioaccumulation of metal cations by Saccharomyces cerevisiae. Applied Microbiology and Biotechnology. 41, 149-154. [Google Scholar] [Crossref]
18. Buss, H.L., Sak, P.B., Webb, S.M., Brantley, S.L., (2008). Weathering of the Rio Blanco quartz diorite, Luquillo Mountains, Puerto Rico: Coupling oxidation, dissolution, and fracturing. Geochimica et Cosmochimica Acta 72, 4488-4507. [Google Scholar] [Crossref]
19. Caeiro, S., Costa, M.H., Ramos, T.B., Fernandes, F., Silveira, N., Coimbra, A., Painho, M., (2015). Assessing heavy metal contamination in Sado Estuary sediment: An index analysis approach. Ecol. Indicators. 5, 151-169. [Google Scholar] [Crossref]
20. Carter, M.R., Gregorich E.G., (2008). Soil Sampling and Methods of Analysis. Second Edition, CRC Press Taylor & Francis Group. 1-173. [Google Scholar] [Crossref]
21. Caspah, K.M., Manny, M., Morgan, M., (2016). Health risk assessment of heavy metals in soils from witwatersrand gold mining basin, South Africa. Int.J. Environ. Res. Public Health. 13, 663. [Google Scholar] [Crossref]
22. Castaing, C. Feybesse, J.L., Thiéblemont, D., Triboulet, C., Chèvremont, P., (1994). Palaeogeographical reconstructions of the Pan-African/Brasiliano orogen: closure of an oceanic domain or intracontinental convergence between major blocks. Precambrian Research. 69, 1-4. [Google Scholar] [Crossref]
23. Cazalet, M.L., (2012). Caractérisation physico-chimique d’un sédiment marin traité aux liants hydrauliques : Évaluation de la mobilité potentielle des polluants inorganiques. Thèse de Doctorat de l'Institut National des Sciences Appliquées de Lyon, 1-226. [Google Scholar] [Crossref]
24. Chiffoleau, J.F., Claisse, D., Cossa, D., Ficht, A., Gonzalez, J.L., Guyot, T., Michel, P., Miramand, P., Oger, C., Petit, F., (2001) La contamination métallique. Programme scientifique Seine-Aval, 8-La contamination métallique. ALT Brest, 1-39. [Google Scholar] [Crossref]
25. Chiroma, T.M., Ebewele, R.O., Hymore, F.K., (2014). Comparative assessement of heavy metal levels in soil, vegetables and urban grey waste water used for irrigation in Yola and Kano. Int.Ref. J. Eng. Sci. 3: 1-9. [Google Scholar] [Crossref]
26. Chukwu, A., Oji, K., (2018). Assessment of Pb, Zn, As, Ni, Cu, Cr and Cd in Agricultural Soils around Settlements of Abandoned Lead-Zinc Mine in Mkpuma Ekwoku, South-eastern, Nigeria. J. Appl. Sci. Environ. Manage. 22 (9) 1485 –1488. [Google Scholar] [Crossref]
27. Cossa, D., (1989). Cadmium in Mytilus Spp: Worldwide Survey and Relationship between seawater and Mussel Content. Marine environmental research. 26(4), 265-284. [Google Scholar] [Crossref]
28. Crentsil, B.K., EWUSI, A., (2016). Heavy metals contamination and human health risk assessment around Obuasi gold mine in Ghana. Environ. Monit. Assess. 188, 261-261. [Google Scholar] [Crossref]
29. Crundwell, F.K. (2014). The mechanism of dissolution of minerals in acidic and alkaline solutions: Part I - A new theory of non-oxidation dissolution. Hydrometallurgy 149, 252-264. [Google Scholar] [Crossref]
30. Csavina, J., Field, J., Taylor, M., Gao, S., Landázuri, A., Betterton, E., Sáez, A.E., ( 2012). A review on the importance of metals and metalloids in atmospheric dust and aerosol from mining operations. Sci. Total Environ. 433, 58–73. [Google Scholar] [Crossref]
31. Dallou, G.B., Louis, N., Abdourahimi, D. B., Saïdou, N.N.I., Boniface K., Godfroy K., (2018). Environmental Pollution by Heavy Metals in the Gold Mining. American Journal of Environmental Sciences. 14 (5), 212-225. [Google Scholar] [Crossref]
32. Dong, X., Li, C., Li, J., Wang, J., Liu, S., & Ye, B. (2010,). A novel approach for soil contamination assessment from heavy metal pollution: A linkage between discharge and adsorption. . J. Hazard. Mater. , 175, 1022–1030. [Google Scholar] [Crossref]
33. Emmanuel, A., Cobbina, S. J., Adomako, D., Duwiejuah, A. B., Asare, W., (2014). Assessment of heavy metals concentration in soils around oil filling and service stations in the Tamale Metropolis. Afri.J. Environ. Sci. Techn. 8, 256-266. [Google Scholar] [Crossref]
34. Ezeh H.N., Chukwu E., (2011). Small scale mining and heavy metals pollution of agricultural soil. Nig. J. Geol. Mining Res.3(4), 87-104. [Google Scholar] [Crossref]
35. Fijałkowski, K., Kacprzak, M., Grobelak, A., Placek, A., (2012). The Influence of Selected Soil Parameters on the Mobility of Heavy Metals in Soils. . Inzynieria i Ochrona Srodowiska. 5, 81-92. [Google Scholar] [Crossref]
36. Funoh, K. (2014). The impacts of artisanal gold mining on local livelihoods and the environ,ent in the forested areas of cameroun. Working paper 150. CIFOR. 25-26. [Google Scholar] [Crossref]
37. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans (2012). Arsenic, Metals, Fibers and Dust. Vol. 100C. In: International Agency for Research on Cancer, Lyon, France, 46-53. [Google Scholar] [Crossref]
38. Gao, J., Du, F., Li, W., Han, J., Wang, X., Bao, J., Fan, A.P., (2016). Content and accumulation characteristics of heavy metals in dominant plants in Xiao Bai He Area of the Yellow River Wetland. . J Agro-Environ Sci. 35 (11), 2180–2186. [Google Scholar] [Crossref]
39. Garnier, J., Quantin, C., Echevarria, G., Becquer, T., (2009). Assessing chromate availability in tropical ultramafic soils using isotopic exchange kinetics. Journal of Soils and Sediments. 9(5), 468–475,. [Google Scholar] [Crossref]
40. Getaneh, W., Alemayehu, T., (2006 ). Metal contamination of the environment by placer and primary gold mining in the Adola region of southern Ethiopia. Environmental Geology, , 50(3), 339-352. [Google Scholar] [Crossref]
41. Gong, Q., Jun, D., Yunchuan, X., Qingfei, W., Liqiang, Y., (2008). Calculating pollution indices by heavy metals in ecological geochemistry assessment and a case study in parks of Beijing. Journal of China University of Geosciences. 19, 230–241. [Google Scholar] [Crossref]
42. Gupta, A.K., Sinha, S., (2007). Phytoextraction Capacity of the Plants Growing on Tannery Sludge Dumping Sites. Bioresource Technology. 98, 1788-1794. [Google Scholar] [Crossref]
43. Gyamfi, E., Appiah-Adjei, E.K., Adjei, K.A., (2019). potential heavy metal illution of soil and water resources from artisanal mining in Kokoteasua, Ghana. ground water for sustainable development, 8,450-456. [Google Scholar] [Crossref]
44. Hakanson, L., (1980). An Ecological Risk Index for Aquatic Pollution Control, a Sediment-Ecological Approach. Water. 14, 975-1001. [Google Scholar] [Crossref]
45. Jamilu, S.E., Ntale, M., Origa, H.O., (2014). Physico-Chemical Characteristics of Copper Tailings and Pyrite Soils in Western Uganda: Implication for Phytoremediation.. International Journal of Environmental Monitoring and Analysis. 2(4), 191-198. [Google Scholar] [Crossref]
46. Jiang, X., Lu, W.X., Zhao, H.Q., Yang, Q.C., Yang, Z.P., (2014). Potential ecological risk assessment and prediction of soil heavy-metal pollution around coal gangue dump. Nat. Hazards Earth Syst. Sci.14, 1599–1610. [Google Scholar] [Crossref]
47. Kabir S.A., Hassan, M.S., Abbas, M.A., Kura, A.M., (2017). Assessment of heavy metals contamination of soil and water around abandoned Pb-Zn mines in Yelu, Alkaleri Local Government Area of Bauchi State, Nigeria. Research Journal of Public and Environmental Health, 4(5), 72-77. [Google Scholar] [Crossref]
48. Khan, M. N., Wasim, A.A., Sarwar, A., Rasheed, M.F., ( 2011). Assessment of heavy metal toxicants in the roadside soil along the N-5, national highway, Pakistan. . Environ. Monit. Assess. 182, 587–595. [Google Scholar] [Crossref]
49. Kim, H., Cho, K., Purev, O., Choi, N., Lee, J., (2022). Remediation of Toxic Heavy Metal Contaminated Soil by Combining aWashing Ejector Based on Hydrodynamic Cavitation and Soil Washing Process. Int. J. Environ.Res. Public Health. 19, 786. [Google Scholar] [Crossref]
50. Kloke, A. (1979). Content of arsenic, cadmium, chromium,fluorine, lead, mercury, and nickel in plants grown on contaminated soils, United Nations-ECE symposium, Geneva. 51–53. [Google Scholar] [Crossref]
51. Kong, M., Huang, L., Li, L., Zhang, Z., Zheng, S., Wang, M. (2014). Effects of oxalic acid and citric acids on the tree clays mineral after incubation. Apply clay science. 99, 207-124. [Google Scholar] [Crossref]
52. Lazo, D.E., Dyer, L.G. , Alorro, R.D., (2017). Silicate, phosphate and carbonate mineral dissolution behaviour in the presence of organic acids: A review. Minerals Engineering. 100, 115-123. [Google Scholar] [Crossref]
53. Lee, P.K., Yu, S., Jeong, Y.-J., Seo, J., Choi, S., & Yoon, B.-Y. ( 2019). Source identification of arsenic contamination in agricultural soils surrounding a closed Cu smelter, South Korea. . Chemosphere. 217, 183–194. [Google Scholar] [Crossref]
54. Léopold, E. N., Sabine, D. D., Jung, M. C., (2016). Physical and Metals Impact of Traditional Gold Mining on Soils in Kombo-Laka Area (Meiganga, Cameroon). International Journal of Geosciences. 7, 1102-1121. [Google Scholar] [Crossref]
55. Li, W., Wang, F., Yang, W., Cui, Y., Fan, A., Miao, C., (2017). Pollution assessment and source apportionment of heavy metals in NanHai Wetland soil of Baotou City. Ecology Environ Sci. , 26(11),1977–1984. [Google Scholar] [Crossref]
56. Long, E.R., MacDonald, D.D., Smith, S.L., Calder, F.D. (1995). Incidence of adverse biological effects within ranges of chemical concentrations in marine and estuarine. Environmental Management. 19, 81–97. [Google Scholar] [Crossref]
57. Lorenzo, F., Alonso, A., Pellicer, M.J., Pérez-Arlucea, M., (2007 ). Historical Analysis of Heavy Metal Pollution in Three Estuaries on the North Coast of Galicia (NW Spain). Environmental Geology. 52, 789-802. [Google Scholar] [Crossref]
58. Luo, T., Ding, Y., Sun, J., Zou, W., Zhou, F., ( 2018). Pollution characteristics and assessment of heavy metals in wetlandsoil in the area of northern Jiangsu Province. . Environ Chem.., 37(5), 984–993. [Google Scholar] [Crossref]
59. Mambou, N.L.L., Mache, J.R., Ayiwouo, N.M., Takougang, K.S., Abende, S.R.Y., Roukaiyatou, S., (2020). Caracterization of Mining Waste from the Betare-Oya Gold Area (East Cameroon) and an Adsorption Test by Sabga Smectite (North-West Cameroon). Scientifica . 1-12. [Google Scholar] [Crossref]
60. Mandeng, E.P.B., Bondjè-Bidjeck, L.M., Ekoa-Bessa, A.Z., Ntomb, Y.D., Wassouo-Wadjou, J., Edjengte-Doumo, E.P. Bitom D.L., (2019). Contamination and risk assessment of heavy metals, and uranium of sediments in two watersheds in Abiete-Toko gold district, Southern Cameroon. Heliyon. 5, (10), e02591. [Google Scholar] [Crossref]
61. Marta, M., Mapani, B.S., Kamona, A.F., Ružičić, S., Mapaure, I., Chimwamurombe, P.M., (2014). Assessment of agricultural soil by potentially toxic metals dispersed from improperly disposed tailings, Kombat mine. Namibia Journal of geochemical exploration. 144, 409-420. [Google Scholar] [Crossref]
62. Matini, L., Ongoka, P.R., Tathy, J.P., (2011). Heavy metals in soil on spoil heap of an abandaoned lead ore treatment plant SE Congo Brzzaville. African journal of environmental science and technology. 5(2), 89-97. [Google Scholar] [Crossref]
63. Mmaduakor, E.C., Umeh, C.T., Morah, J.E., Omokpariola, D.O., Ekwuofu, A.A., Onwuegbuokwu, S.S., (2022). Pollution status, health risk assessment of potentially toxic elements in soil and their uptake by gongronema latifolium in peri-urban of Ora-Eri, south-eastern Nigeria. Heliyon. 8(8), e10362. [Google Scholar] [Crossref]
64. Mmolawa, K B., Likuku, A.S., Gaboutloeloe, G.K.., (2011). Assessment of heavy metal pollution in soils along major roadside areas in Botswana. . African J.Environ. Sci. Technol. 5, 186-196. [Google Scholar] [Crossref]
65. Mokam, S., Aurelle, B., Tsikam, M.C., (2013). Impact de l'exploitation artisanale de l'or sur les populations de Kambele, région de l'Est Cameroun. Journal du CIMEC, 1-30. [Google Scholar] [Crossref]
66. Mominou, N., Al Issah, Y., Sarki, B., Kah, E. (2018). Physicochemical Characterisation of Soils at the Gold Exploitation Sites of Bétaré-Oya District in Cameroon and Pollution Evaluation. Open Journal of Inorganic Chemi. 81-90. [Google Scholar] [Crossref]
67. Mushtaha, A.L.İ., Elhagwa, A., Elfaki, J., Sulieman, M., (2017). Influence of the artisanal gold mining on soil contamination with heavy metals: A case study from Dar-Mali locality, North of Atbara, River Nile State. Sudan. Eurasian J. Soil Sci. 6, 28-36. [Google Scholar] [Crossref]
68. Benson, N.U., Adedapo, A.E., Fred-Ahmadu, O.H., Williams, A.B., Udosen, E.D., Ayejuyo, O.O., Olajire, A.A., (2018). New ecological risk indices for evaluating heavy metalscontamination in aquatic sediment: A case study of the Gulf of Guinea. Regional Studies in Marine Science . 18, 44–56. [Google Scholar] [Crossref]
69. Nzenti, J.P., Barbey, P., Macaudiere, J., Soba, D., (1988). Origin and evolution of the late Precambrian high-grade Yaounde gneisses (Cameroon). . Precambrian research. 38(2), 91-109. [Google Scholar] [Crossref]
70. Obiora, S.C., Chukwu, A., Toteu, S.F., Davies, T.C., (2016). Assesment of heavy metal contamination in soils around Lead (Pb) - Zinc (Zn) mining areas in Enyigba. Southeastern Nigeria. J. Geol. Soc. India. 87, 453-462. [Google Scholar] [Crossref]
71. Oyourou, J.N., McCrindle, R., Combrinck, S., Fourie, C.J.S., (2019). investigation of of Zn and Pb contamination of soil at the abandoned Ededale mine, amelodi (Pretoria South Africa) using a field portable spectrometer. Journal of southen african institute of miningg and metallurgy. 119(1), 55-62. [Google Scholar] [Crossref]
72. Pawan, K. (2012). Heavy Metals in Environment. Saarbrucken, Germany. First Edition. Lambert Academic Publishing GmbH and Co. [Google Scholar] [Crossref]
73. PCD. (2019). Plan Communal de Développement de Batouri. Commune de BATOURI BP 42.6-407. [Google Scholar] [Crossref]
74. Pejman, A., Bidhendi, G.N., Ardestani, M., Saeedi, M., Baghvand, A., (2015). A new index for assessing heavy metals contamination in sediments: A case study. Ecological Indicators. 58, 365–373. [Google Scholar] [Crossref]
75. Penaye, J., Hell, J.V., (2013). Abandoned artisanal mining sites of Eastern Cameroon: environmental problems and Cameroon legislation:. Yaounde: institute for geological and mining research. Environmental problems and Cameroon regulation. In Conférence Johannesburg. [Google Scholar] [Crossref]
76. Poidevin, A., Ngako, V., Nnange, J. M., & Njanko, T. (2003). Pan-African tectonic evolution in central and southern Cameroon: transpression and transtension during sinistral shear movements. Journal of African Earth Sciences, 36(3), 207-214. [Google Scholar] [Crossref]
77. Ramahlo, M. N. (2013). Physico-chemical and biological characterization of soils from selected farmlands around three mining sites in Phalaborwa, Limpopo province (Doctoral dissertation, University of Limpopo (Turfloop Campus)). [Google Scholar] [Crossref]
78. Rohde, R. A., Muller, R. A., (2015). Air pollution in China: mapping of concentrations and sources. PloS one.10(8), e0135749. [Google Scholar] [Crossref]
79. Rossman, T. G., (2003). Mechanism of arsenic carcinogenesis: an integrated approach. Mutation Research/Fundamental and Molecular Mechanisms of Mutagenesis,.533(1-2), 37-65. [Google Scholar] [Crossref]
80. Salati, S., Moore, F.,(2010). Assessment of heavy metal concentration in the Khoshk River water and sediment, Shiraz. Southwest Iran. Environmental monitoring and assessment.164(1), 677-689. [Google Scholar] [Crossref]
81. Sawant, S.Y., Pawar, R.R., Lee S.M., Cho M.H., (2017). Binder-free production of 3D N-doped porous carbon cubes for efficient Pb2+ removal through batch and fixed bed adsorption. J. Clean. Prod. 168, 290-301. [Google Scholar] [Crossref]
82. Sijin L., Wang, Y., Teng, Y., Yu, X., (2015). Heavy metal pollution and ecological risk assessment of the paddy soils near a zinc-lead mining area in Hunan. Environmental monitoring and assessment. 187(10), 1-12. [Google Scholar] [Crossref]
83. Singh, A., Harrison, A., (1985). Standardized principal components. International journal of remote sensing, , 6(6), 883-896. [Google Scholar] [Crossref]
84. Syed, R.H., Khanam, D., Adyel, T.M., Islam, M.S., Ahsan, M.A., Akbor, M.A. ( 2012). Assessment of Heavy Metal Contamination of Agricultural Soil around Dhaka Export Processing Zone (DEPZ). Bangladesh. Appl. Sci. 2, 584-601. [Google Scholar] [Crossref]
85. Tariq, J., Ahmad, N., Mashiatullah, A., (2018). Heavy Metals Contamination and Ecological Risk Assessment in Surface Sediments of Namal Lake, Pakistan. Polish journal of environmental studies, 27(2). [Google Scholar] [Crossref]
86. Taylor, S.R., McLennan, S.M., (1985). The Continental Crust: Its Composition and Evolution. Oxford.: Blackwell Scientific Publication. [Google Scholar] [Crossref]
87. Tchouankam, J. K., Bertrand, M. M., Elie-Constant, B., Bernard, T., Gilbert, N., François, A. Y. R., Jacques, K.J.E., (2020). Economic Potential of Gold in Batouri (Eastern Cameroon). Earth Science Research. 21-27. [Google Scholar] [Crossref]
88. Tchounwou, P.B., Yedjou, C.G., Patlolla, A.K., Sutton, D. J., (2012). Heavy metal toxicity and the environment. Molecular, clinical and environmental toxicology.133-164. [Google Scholar] [Crossref]
89. Tehna, N., Daniel, N. F., Jacques, E., Marc, M. E. J., Sylvie, N. T., Cheo, S. E., Paul, B., (2015). Impending Pollution of Betare Oya Opencast Mining Environment (Eastern Cameroon). Journal of Environmental Science and Engineering , 4 37-46. [Google Scholar] [Crossref]
90. Teixeira, R.A., de Souza, E.S., Ferreira, J.R., Fernandes, A.R., (2018). Potentially toxic elements in soils and contamination indices at the Serra Pelada gold mine, Para, Brazil. Bioscience Journal. 34(6), 1477-1487. [Google Scholar] [Crossref]
91. Tirmizi, S.A., Wattoo, F.H., Wattoo, M.H.S., Khokhar, M.N., Iqbal, J., (2005). Analytical investigation of soil inorganic elements in cotton cultivated areas of Vehari-Pakistan. Journal of the Chemical Society of Pakistan. 27(6), 606-610. [Google Scholar] [Crossref]
92. Tokar E.J., Benbrahim-Tallaa L., Ward J.M., Lunn R., Sams R.L., Waalkes M.P. (2010). Cancer in experimental animals exposed to arsenic and arsenic compounds. Crit. Rev. Toxicol. 40 (10), 912-927. [Google Scholar] [Crossref]
93. Tomlinson, D.L., Wilson, J.G., Harris, C.R., Jeffrey, D.W., (1980). Problems in the assessment of heavy-metal levels in estuaries and the formation of a pollution index. Helgoländer meeresuntersuchungen. 33(1), 566-575. [Google Scholar] [Crossref]
94. Toteu, S.F., Penaye, J., Djomani, Y.P. (2004). Geodynamic evolution of the Pan-African belt in central Africa with special reference to Cameroon. Canadian Journal of Earth Sciences. 41(1), 73-85. [Google Scholar] [Crossref]
95. USEPA. (2013). Toxicity Relationship Analysis Program (TRAP) version 1.22 United States Environmental Protection Agency, . Washington D.C., USA.: Division. Mid-Continent Ecology. [Google Scholar] [Crossref]
96. Van-Schmus, W.R., Oliveira, E.P., Da-Silva-Filho, A.F., Toteu, S.F., Penaye, J., Guimarães, I.P. (2008). Proterozoic links between the Borborema province, NE Brazil, and the central African fold belt. Geological Society, London, Special Publication. 294(1), 69-99. [Google Scholar] [Crossref]
97. Varol, M. (2011). Assessment of heavy metal contamination in sediments of the Tigris River (Turkey) using pollution indices and multivariate statistical techniques. Journal of Hazardous Materials. 195, 355–364. [Google Scholar] [Crossref]
98. Wang, X., Sun, Y., Li, S., Wang, H., (2019). Spatial distribution and ecological risk assessment of heavy metals in soil from the Raoyanghe Wetland, China. PLoS ONE , 14(8), e0220409. [Google Scholar] [Crossref]
99. Weihua, G., Liu, X., Liu, Z., Li, G., (2010). Pollution and Potential Ecological Risk Evaluation of Heavy Metals in the Sediments around Dongjiang Harbor, Tianjin. Procedia Environmental Sciences. 2, 729–736. [Google Scholar] [Crossref]
100. WHO. (1996.). Trace Elements in Human Nutrition and Health. Geneva, Switzerland. ISBN-13: 9241561734, 361. [Google Scholar] [Crossref]
101. Wu, J., West, L. J., Stewart, D.I., (2002). Effect of humic substances on Cu (II) solubility in kaolin-sand soil. Journal of Hazardous Materials. 94(3), 223-238. [Google Scholar] [Crossref]
102. Guan, Y., Shao, C., Ju, M., (2014). Heavy metal contamination assessment and partition for industrial and mining gathering areas. International journal of environmental research and public health. 11(7), 7286-7303. [Google Scholar] [Crossref]
103. Yu, L., Cheng, J., Zhan, J., Jiang, A., (2016). Environmental quality and sources of heavy metals in the topsoil based on multivariate statistical analyses: a case study in Laiwu City, Shandong Province, China. Natural Hazards. 81(3), 1435-1445. [Google Scholar] [Crossref]
104. Zhang, X., Zhou, T.F., Yang, X.F., Yin, H.Q., Xiao, Z.H., (2005). Study on assessment methods of heavy metal pollution in river sediments. J. Hefei Univ. Technol. 28, 1419-1423. [Google Scholar] [Crossref]
105. Zhao, Q., Qi-xin, X. U., Kai, Y., (2005). Application of Potential Ecological Risk Index in Soil Pollution of Typical Polluting Industries. Journal of Eastchina Normal University (Natural Science). 1, 110-115. [Google Scholar] [Crossref]
106. Zhou, J., Dang, Z., Cai, M., Liu, C., (2007). Soil heavy metal pollution around the Dabaoshan mine,China. International Journal of Environmental Research and Public Health. 588–594. [Google Scholar] [Crossref]
107. Abdullateef, J., Agbaji1, E.B., Ajibola1, V.O., Funtua, M.A., (2020). Application of Pollution Load Indices, Enrichment Factors,Contamination Factor and Health Risk Assessment of soils. Open J Anal Bioanal Chem. 4(1), 011-019. [Google Scholar] [Crossref]
108. Abhijit, M., Maiti, R., (2018). Geochemical contamination in the mine affected soil of Raniganj Coalfield–A river basin scale assessment. Geoscience Frontiers, 9(5), 1577-1590. [Google Scholar] [Crossref]
109. Abrahim, G.M.S., Parker, R. J., ( 2008). Assessment of heavy metal enrichment factors and the degree of contamination in marine sediments from Tamaki Estuary, Auckland, New Zealand. Environmental Monitoring and Assessment. 136, 227–238. [Google Scholar] [Crossref]
110. Adamu, C.I., Nganje, T.N., (2010). Heavy metal contamination of surface soil in relationship to land use patterns: A case study of Benue State, Nigeria. Materials Sciences and Applications. 1, 127–134. [Google Scholar] [Crossref]
111. Adenuga, A.A., Olufemi, D.A., Olajide, O.D., Eludoyin, A.O., Idowu, O.O., (2022). Environmental impact and health risk assessment of potentially toxic metals emanating from different anthropogenic activities related to E-wastes. Heliyon. 8(8), e10296. [Google Scholar] [Crossref]
112. Affum, A.O., Osae, S.D., Kwaansa-Ansah, E.E., Miyittah, M.K., (2020). Quality assessment and potential health risk of heavy metals in leafy and non-leafy vegetables irrigated with groundwater and municipal-waste-dominated stream in the Western Region, Ghana. Heliyon. Volume 6 (12), e05829. [Google Scholar] [Crossref]
113. Awasthi, G., Nagar, V., K.K., Rajput, V., Bauer, T., Srivastava, S., (2022). Sustainable Amelioration of Heavy Metals in Soil Ecosystem:Existing Developments to Emerging Trends. Minerals. 12, 85. [Google Scholar] [Crossref]
114. Axtmann, E.V., Luoma, S.N., (1991). Large-Scale Distribution of Metal Contamination in the Fine-Grained Sediments of the Clark Fork River, Montana, U.S.A. Applied Geochemistry . 6, 75-88. [Google Scholar] [Crossref]
115. Ayiwouo, M.N., Mambou, L.L.N., Takougang, S.K., Ngounouno, I., (2022). Spatio‑temporal variation and assessment of trace metal contamination in sediments along the Lom River in the gold mining site of Gankombol (Adamawa Cameroon). Environmental Earth Sciences. 81(379), 1-20. [Google Scholar] [Crossref]
116. Babelewska, A., (2010). The impact of industrial emissions on heavy metal and sulphur contamination level within the area of the projected Jurassic National Park. Pra˛dnik Studies and Reports of the Prof Władysław Szafer Museum. 20, 135–145. [Google Scholar] [Crossref]
117. Baby, J., Raj, J.S., Biby, E.T., Sankarganesh, P., Jeevitha, M.V., Ajisha, S.U., Rajan, S.S., (2010). Toxic effect of heavy metals on aquatic environment. Int. J. Biol. Chem. Sci. 4, 939-952. [Google Scholar] [Crossref]
118. Bade, R., Oh, S., Shin, W., Hwang, I., (2013,). Human health risk assessment of soils contaminated with tal(loid)s by using DGT uptake: A case study of a former Korean metal refinery site. Hum.Ecol. Risk Assessment , 19, 767–777. [Google Scholar] [Crossref]
119. Baird, C., Michael, C., (2012). Environmental chemistry. Fifth Edition. Macmillan Higher Education. [Google Scholar] [Crossref]
120. Baker, D.E., Alloway, B.J., (2000). Analysis of heavy metals in soil. Int. J. Agric. Policy Res. 1(2), 151-196. [Google Scholar] [Crossref]
121. Bhargava, A., Carmona, F.F., Bhargava, M., Srivastava, S., (2012.). Approachesforenhanced phytoextractionofheavymetals. J.Environ.Manage. 105,103–120. [Google Scholar] [Crossref]
122. Banunle, A., Fei-Baffoe, B., Otchere, K.G., (2018). Determination of the Physico-Chemical Properties and Heavy Metal Status of the Tano River along the Catchment of the Ahafo Mine in the Brong-Ahafo Mine. Ghana. J Environ Anal Toxicol. 8(3), 2-11. [Google Scholar] [Crossref]
123. Brady D, Duncan J.R., (1994). Bioaccumulation of metal cations by Saccharomyces cerevisiae. Applied Microbiology and Biotechnology. 41, 149-154. [Google Scholar] [Crossref]
124. Buss, H.L., Sak, P.B., Webb, S.M., Brantley, S.L., (2008). Weathering of the Rio Blanco quartz diorite, Luquillo Mountains, Puerto Rico: Coupling oxidation, dissolution, and fracturing. Geochimica et Cosmochimica Acta 72, 4488-4507. [Google Scholar] [Crossref]
125. Caeiro, S., Costa, M.H., Ramos, T.B., Fernandes, F., Silveira, N., Coimbra, A., Painho, M., (2015). Assessing heavy metal contamination in Sado Estuary sediment: An index analysis approach. Ecol. Indicators. 5, 151-169. [Google Scholar] [Crossref]
126. Carter, M.R., Gregorich E.G., (2008). Soil Sampling and Methods of Analysis. Second Edition, CRC Press Taylor & Francis Group. 1-173. [Google Scholar] [Crossref]
127. Caspah, K.M., Manny, M., Morgan, M., (2016). Health risk assessment of heavy metals in soils from witwatersrand gold mining basin, South Africa. Int.J. Environ. Res. Public Health. 13, 663. [Google Scholar] [Crossref]
128. Castaing, C. Feybesse, J.L., Thiéblemont, D., Triboulet, C., Chèvremont, P., (1994). Palaeogeographical reconstructions of the Pan-African/Brasiliano orogen: closure of an oceanic domain or intracontinental convergence between major blocks. Precambrian Research. 69, 1-4. [Google Scholar] [Crossref]
129. Cazalet, M.L., (2012). Caractérisation physico-chimique d’un sédiment marin traité aux liants hydrauliques : Évaluation de la mobilité potentielle des polluants inorganiques. Thèse de Doctorat de l'Institut National des Sciences Appliquées de Lyon, 1-226. [Google Scholar] [Crossref]
130. Chiffoleau, J.F., Claisse, D., Cossa, D., Ficht, A., Gonzalez, J.L., Guyot, T., Michel, P., Miramand, P., Oger, C., Petit, F., (2001) La contamination métallique. Programme scientifique Seine-Aval, 8-La contamination métallique. ALT Brest, 1-39. [Google Scholar] [Crossref]
131. Chiroma, T.M., Ebewele, R.O., Hymore, F.K., (2014). Comparative assessement of heavy metal levels in soil, vegetables and urban grey waste water used for irrigation in Yola and Kano. Int.Ref. J. Eng. Sci. 3: 1-9. [Google Scholar] [Crossref]
132. Chukwu, A., Oji, K., (2018). Assessment of Pb, Zn, As, Ni, Cu, Cr and Cd in Agricultural Soils around Settlements of Abandoned Lead-Zinc Mine in Mkpuma Ekwoku, South-eastern, Nigeria. J. Appl. Sci. Environ. Manage. 22 (9) 1485 –1488. [Google Scholar] [Crossref]
133. Cossa, D., (1989). Cadmium in Mytilus Spp: Worldwide Survey and Relationship between seawater and Mussel Content. Marine environmental research. 26(4), 265-284. [Google Scholar] [Crossref]
134. Crentsil, B.K., EWUSI, A., (2016). Heavy metals contamination and human health risk assessment around Obuasi gold mine in Ghana. Environ. Monit. Assess. 188, 261-261. [Google Scholar] [Crossref]
135. Crundwell, F.K. (2014). The mechanism of dissolution of minerals in acidic and alkaline solutions: Part I - A new theory of non-oxidation dissolution. Hydrometallurgy 149, 252-264. [Google Scholar] [Crossref]
136. Csavina, J., Field, J., Taylor, M., Gao, S., Landázuri, A., Betterton, E., Sáez, A.E., ( 2012). A review on the importance of metals and metalloids in atmospheric dust and aerosol from mining operations. Sci. Total Environ. 433, 58–73. [Google Scholar] [Crossref]
137. Dallou, G.B., Louis, N., Abdourahimi, D. B., Saïdou, N.N.I., Boniface K., Godfroy K., (2018). Environmental Pollution by Heavy Metals in the Gold Mining. American Journal of Environmental Sciences. 14 (5), 212-225. [Google Scholar] [Crossref]
138. Dong, X., Li, C., Li, J., Wang, J., Liu, S., & Ye, B. (2010,). A novel approach for soil contamination assessment from heavy metal pollution: A linkage between discharge and adsorption. . J. Hazard. Mater. , 175, 1022–1030. [Google Scholar] [Crossref]
139. Emmanuel, A., Cobbina, S. J., Adomako, D., Duwiejuah, A. B., Asare, W., (2014). Assessment of heavy metals concentration in soils around oil filling and service stations in the Tamale Metropolis. Afri.J. Environ. Sci. Techn. 8, 256-266. [Google Scholar] [Crossref]
140. Ezeh H.N., Chukwu E., (2011). Small scale mining and heavy metals pollution of agricultural soil. Nig. J. Geol. Mining Res.3(4), 87-104. [Google Scholar] [Crossref]
141. Fijałkowski, K., Kacprzak, M., Grobelak, A., Placek, A., (2012). The Influence of Selected Soil Parameters on the Mobility of Heavy Metals in Soils. . Inzynieria i Ochrona Srodowiska. 5, 81-92. [Google Scholar] [Crossref]
142. Funoh, K. (2014). The impacts of artisanal gold mining on local livelihoods and the environ,ent in the forested areas of cameroun. Working paper 150. CIFOR. 25-26. [Google Scholar] [Crossref]
143. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans (2012). Arsenic, Metals, Fibers and Dust. Vol. 100C. In: International Agency for Research on Cancer, Lyon, France, 46-53. [Google Scholar] [Crossref]
144. Gao, J., Du, F., Li, W., Han, J., Wang, X., Bao, J., Fan, A.P., (2016). Content and accumulation characteristics of heavy metals in dominant plants in Xiao Bai He Area of the Yellow River Wetland. . J Agro-Environ Sci. 35 (11), 2180–2186. [Google Scholar] [Crossref]
145. Garnier, J., Quantin, C., Echevarria, G., Becquer, T., (2009). Assessing chromate availability in tropical ultramafic soils using isotopic exchange kinetics. Journal of Soils and Sediments. 9(5), 468–475,. [Google Scholar] [Crossref]
146. Getaneh, W., Alemayehu, T., (2006 ). Metal contamination of the environment by placer and primary gold mining in the Adola region of southern Ethiopia. Environmental Geology, , 50(3), 339-352. [Google Scholar] [Crossref]
147. Gong, Q., Jun, D., Yunchuan, X., Qingfei, W., Liqiang, Y., (2008). Calculating pollution indices by heavy metals in ecological geochemistry assessment and a case study in parks of Beijing. Journal of China University of Geosciences. 19, 230–241. [Google Scholar] [Crossref]
148. Gupta, A.K., Sinha, S., (2007). Phytoextraction Capacity of the Plants Growing on Tannery Sludge Dumping Sites. Bioresource Technology. 98, 1788-1794. [Google Scholar] [Crossref]
149. Gyamfi, E., Appiah-Adjei, E.K., Adjei, K.A., (2019). potential heavy metal illution of soil and water resources from artisanal mining in Kokoteasua, Ghana. ground water for sustainable development, 8,450-456. [Google Scholar] [Crossref]
150. Hakanson, L., (1980). An Ecological Risk Index for Aquatic Pollution Control, a Sediment-Ecological Approach. Water. 14, 975-1001. [Google Scholar] [Crossref]
151. Jamilu, S.E., Ntale, M., Origa, H.O., (2014). Physico-Chemical Characteristics of Copper Tailings and Pyrite Soils in Western Uganda: Implication for Phytoremediation.. International Journal of Environmental Monitoring and Analysis. 2(4), 191-198. [Google Scholar] [Crossref]
152. Jiang, X., Lu, W.X., Zhao, H.Q., Yang, Q.C., Yang, Z.P., (2014). Potential ecological risk assessment and prediction of soil heavy-metal pollution around coal gangue dump. Nat. Hazards Earth Syst. Sci.14, 1599–1610. [Google Scholar] [Crossref]
153. Kabir S.A., Hassan, M.S., Abbas, M.A., Kura, A.M., (2017). Assessment of heavy metals contamination of soil and water around abandoned Pb-Zn mines in Yelu, Alkaleri Local Government Area of Bauchi State, Nigeria. Research Journal of Public and Environmental Health, 4(5), 72-77. [Google Scholar] [Crossref]
154. Khan, M. N., Wasim, A.A., Sarwar, A., Rasheed, M.F., ( 2011). Assessment of heavy metal toxicants in the roadside soil along the N-5, national highway, Pakistan. . Environ. Monit. Assess. 182, 587–595. [Google Scholar] [Crossref]
155. Kim, H., Cho, K., Purev, O., Choi, N., Lee, J., (2022). Remediation of Toxic Heavy Metal Contaminated Soil by Combining aWashing Ejector Based on Hydrodynamic Cavitation and Soil Washing Process. Int. J. Environ.Res. Public Health. 19, 786. [Google Scholar] [Crossref]
156. Kloke, A. (1979). Content of arsenic, cadmium, chromium,fluorine, lead, mercury, and nickel in plants grown on contaminated soils, United Nations-ECE symposium, Geneva. 51–53. [Google Scholar] [Crossref]
157. Kong, M., Huang, L., Li, L., Zhang, Z., Zheng, S., Wang, M. (2014). Effects of oxalic acid and citric acids on the tree clays mineral after incubation. Apply clay science. 99, 207-124. [Google Scholar] [Crossref]
158. Lazo, D.E., Dyer, L.G. , Alorro, R.D., (2017). Silicate, phosphate and carbonate mineral dissolution behaviour in the presence of organic acids: A review. Minerals Engineering. 100, 115-123. [Google Scholar] [Crossref]
159. Lee, P.K., Yu, S., Jeong, Y.-J., Seo, J., Choi, S., & Yoon, B.-Y. ( 2019). Source identification of arsenic contamination in agricultural soils surrounding a closed Cu smelter, South Korea. . Chemosphere. 217, 183–194. [Google Scholar] [Crossref]
160. Léopold, E. N., Sabine, D. D., Jung, M. C., (2016). Physical and Metals Impact of Traditional Gold Mining on Soils in Kombo-Laka Area (Meiganga, Cameroon). International Journal of Geosciences. 7, 1102-1121. [Google Scholar] [Crossref]
161. Li, W., Wang, F., Yang, W., Cui, Y., Fan, A., Miao, C., (2017). Pollution assessment and source apportionment of heavy metals in NanHai Wetland soil of Baotou City. Ecology Environ Sci. , 26(11),1977–1984. [Google Scholar] [Crossref]
162. Long, E.R., MacDonald, D.D., Smith, S.L., Calder, F.D. (1995). Incidence of adverse biological effects within ranges of chemical concentrations in marine and estuarine. Environmental Management. 19, 81–97. [Google Scholar] [Crossref]
163. Lorenzo, F., Alonso, A., Pellicer, M.J., Pérez-Arlucea, M., (2007 ). Historical Analysis of Heavy Metal Pollution in Three Estuaries on the North Coast of Galicia (NW Spain). Environmental Geology. 52, 789-802. [Google Scholar] [Crossref]
164. Luo, T., Ding, Y., Sun, J., Zou, W., Zhou, F., ( 2018). Pollution characteristics and assessment of heavy metals in wetlandsoil in the area of northern Jiangsu Province. . Environ Chem.., 37(5), 984–993. [Google Scholar] [Crossref]
165. Mambou, N.L.L., Mache, J.R., Ayiwouo, N.M., Takougang, K.S., Abende, S.R.Y., Roukaiyatou, S., (2020). Caracterization of Mining Waste from the Betare-Oya Gold Area (East Cameroon) and an Adsorption Test by Sabga Smectite (North-West Cameroon). Scientifica . 1-12. [Google Scholar] [Crossref]
166. Mandeng, E.P.B., Bondjè-Bidjeck, L.M., Ekoa-Bessa, A.Z., Ntomb, Y.D., Wassouo-Wadjou, J., Edjengte-Doumo, E.P. Bitom D.L., (2019). Contamination and risk assessment of heavy metals, and uranium of sediments in two watersheds in Abiete-Toko gold district, Southern Cameroon. Heliyon. 5, (10), e02591. [Google Scholar] [Crossref]
167. Marta, M., Mapani, B.S., Kamona, A.F., Ružičić, S., Mapaure, I., Chimwamurombe, P.M., (2014). Assessment of agricultural soil by potentially toxic metals dispersed from improperly disposed tailings, Kombat mine. Namibia Journal of geochemical exploration. 144, 409-420. [Google Scholar] [Crossref]
168. Matini, L., Ongoka, P.R., Tathy, J.P., (2011). Heavy metals in soil on spoil heap of an abandaoned lead ore treatment plant SE Congo Brzzaville. African journal of environmental science and technology. 5(2), 89-97. [Google Scholar] [Crossref]
169. Mmaduakor, E.C., Umeh, C.T., Morah, J.E., Omokpariola, D.O., Ekwuofu, A.A., Onwuegbuokwu, S.S., (2022). Pollution status, health risk assessment of potentially toxic elements in soil and their uptake by gongronema latifolium in peri-urban of Ora-Eri, south-eastern Nigeria. Heliyon. 8(8), e10362. [Google Scholar] [Crossref]
170. Mmolawa, K B., Likuku, A.S., Gaboutloeloe, G.K.., (2011). Assessment of heavy metal pollution in soils along major roadside areas in Botswana. . African J.Environ. Sci. Technol. 5, 186-196. [Google Scholar] [Crossref]
171. Mokam, S., Aurelle, B., Tsikam, M.C., (2013). Impact de l'exploitation artisanale de l'or sur les populations de Kambele, région de l'Est Cameroun. Journal du CIMEC, 1-30. [Google Scholar] [Crossref]
172. Mominou, N., Al Issah, Y., Sarki, B., Kah, E. (2018). Physicochemical Characterisation of Soils at the Gold Exploitation Sites of Bétaré-Oya District in Cameroon and Pollution Evaluation. Open Journal of Inorganic Chemi. 81-90. [Google Scholar] [Crossref]
173. Mushtaha, A.L.İ., Elhagwa, A., Elfaki, J., Sulieman, M., (2017). Influence of the artisanal gold mining on soil contamination with heavy metals: A case study from Dar-Mali locality, North of Atbara, River Nile State. Sudan. Eurasian J. Soil Sci. 6, 28-36. [Google Scholar] [Crossref]
174. Benson, N.U., Adedapo, A.E., Fred-Ahmadu, O.H., Williams, A.B., Udosen, E.D., Ayejuyo, O.O., Olajire, A.A., (2018). New ecological risk indices for evaluating heavy metalscontamination in aquatic sediment: A case study of the Gulf of Guinea. Regional Studies in Marine Science . 18, 44–56. [Google Scholar] [Crossref]
175. Nzenti, J.P., Barbey, P., Macaudiere, J., Soba, D., (1988). Origin and evolution of the late Precambrian high-grade Yaounde gneisses (Cameroon). . Precambrian research. 38(2), 91-109. [Google Scholar] [Crossref]
176. Obiora, S.C., Chukwu, A., Toteu, S.F., Davies, T.C., (2016). Assesment of heavy metal contamination in soils around Lead (Pb) - Zinc (Zn) mining areas in Enyigba. Southeastern Nigeria. J. Geol. Soc. India. 87, 453-462. [Google Scholar] [Crossref]
177. Oyourou, J.N., McCrindle, R., Combrinck, S., Fourie, C.J.S., (2019). investigation of of Zn and Pb contamination of soil at the abandoned Ededale mine, amelodi (Pretoria South Africa) using a field portable spectrometer. Journal of southen african institute of miningg and metallurgy. 119(1), 55-62. [Google Scholar] [Crossref]
178. Pawan, K. (2012). Heavy Metals in Environment. Saarbrucken, Germany. First Edition. Lambert Academic Publishing GmbH and Co. [Google Scholar] [Crossref]
179. PCD. (2019). Plan Communal de Développement de Batouri. Commune de BATOURI BP 42.6-407. [Google Scholar] [Crossref]
180. Pejman, A., Bidhendi, G.N., Ardestani, M., Saeedi, M., Baghvand, A., (2015). A new index for assessing heavy metals contamination in sediments: A case study. Ecological Indicators. 58, 365–373. [Google Scholar] [Crossref]
181. Penaye, J., Hell, J.V., (2013). Abandoned artisanal mining sites of Eastern Cameroon: environmental problems and Cameroon legislation:. Yaounde: institute for geological and mining research. Environmental problems and Cameroon regulation. In Conférence Johannesburg. [Google Scholar] [Crossref]
182. Poidevin, A., Ngako, V., Nnange, J. M., & Njanko, T. (2003). Pan-African tectonic evolution in central and southern Cameroon: transpression and transtension during sinistral shear movements. Journal of African Earth Sciences, 36(3), 207-214. [Google Scholar] [Crossref]
183. Ramahlo, M. N. (2013). Physico-chemical and biological characterization of soils from selected farmlands around three mining sites in Phalaborwa, Limpopo province (Doctoral dissertation, University of Limpopo (Turfloop Campus)). [Google Scholar] [Crossref]
184. Rohde, R. A., Muller, R. A., (2015). Air pollution in China: mapping of concentrations and sources. PloS one.10(8), e0135749. [Google Scholar] [Crossref]
185. Rossman, T. G., (2003). Mechanism of arsenic carcinogenesis: an integrated approach. Mutation Research/Fundamental and Molecular Mechanisms of Mutagenesis,.533(1-2), 37-65. [Google Scholar] [Crossref]
186. Salati, S., Moore, F.,(2010). Assessment of heavy metal concentration in the Khoshk River water and sediment, Shiraz. Southwest Iran. Environmental monitoring and assessment.164(1), 677-689. [Google Scholar] [Crossref]
187. Sawant, S.Y., Pawar, R.R., Lee S.M., Cho M.H., (2017). Binder-free production of 3D N-doped porous carbon cubes for efficient Pb2+ removal through batch and fixed bed adsorption. J. Clean. Prod. 168, 290-301. [Google Scholar] [Crossref]
188. Sijin L., Wang, Y., Teng, Y., Yu, X., (2015). Heavy metal pollution and ecological risk assessment of the paddy soils near a zinc-lead mining area in Hunan. Environmental monitoring and assessment. 187(10), 1-12. [Google Scholar] [Crossref]
189. Singh, A., Harrison, A., (1985). Standardized principal components. International journal of remote sensing, , 6(6), 883-896. [Google Scholar] [Crossref]
190. Syed, R.H., Khanam, D., Adyel, T.M., Islam, M.S., Ahsan, M.A., Akbor, M.A. ( 2012). Assessment of Heavy Metal Contamination of Agricultural Soil around Dhaka Export Processing Zone (DEPZ). Bangladesh. Appl. Sci. 2, 584-601. [Google Scholar] [Crossref]
191. Tariq, J., Ahmad, N., Mashiatullah, A., (2018). Heavy Metals Contamination and Ecological Risk Assessment in Surface Sediments of Namal Lake, Pakistan. Polish journal of environmental studies, 27(2). [Google Scholar] [Crossref]
192. Taylor, S.R., McLennan, S.M., (1985). The Continental Crust: Its Composition and Evolution. Oxford.: Blackwell Scientific Publication. [Google Scholar] [Crossref]
193. Tchouankam, J. K., Bertrand, M. M., Elie-Constant, B., Bernard, T., Gilbert, N., François, A. Y. R., Jacques, K.J.E., (2020). Economic Potential of Gold in Batouri (Eastern Cameroon). Earth Science Research. 21-27. [Google Scholar] [Crossref]
194. Tchounwou, P.B., Yedjou, C.G., Patlolla, A.K., Sutton, D. J., (2012). Heavy metal toxicity and the environment. Molecular, clinical and environmental toxicology.133-164. [Google Scholar] [Crossref]
195. Tehna, N., Daniel, N. F., Jacques, E., Marc, M. E. J., Sylvie, N. T., Cheo, S. E., Paul, B., (2015). Impending Pollution of Betare Oya Opencast Mining Environment (Eastern Cameroon). Journal of Environmental Science and Engineering , 4 37-46. [Google Scholar] [Crossref]
196. Teixeira, R.A., de Souza, E.S., Ferreira, J.R., Fernandes, A.R., (2018). Potentially toxic elements in soils and contamination indices at the Serra Pelada gold mine, Para, Brazil. Bioscience Journal. 34(6), 1477-1487. [Google Scholar] [Crossref]
197. Tirmizi, S.A., Wattoo, F.H., Wattoo, M.H.S., Khokhar, M.N., Iqbal, J., (2005). Analytical investigation of soil inorganic elements in cotton cultivated areas of Vehari-Pakistan. Journal of the Chemical Society of Pakistan. 27(6), 606-610. [Google Scholar] [Crossref]
198. Tokar E.J., Benbrahim-Tallaa L., Ward J.M., Lunn R., Sams R.L., Waalkes M.P. (2010). Cancer in experimental animals exposed to arsenic and arsenic compounds. Crit. Rev. Toxicol. 40 (10), 912-927. [Google Scholar] [Crossref]
199. Tomlinson, D.L., Wilson, J.G., Harris, C.R., Jeffrey, D.W., (1980). Problems in the assessment of heavy-metal levels in estuaries and the formation of a pollution index. Helgoländer meeresuntersuchungen. 33(1), 566-575. [Google Scholar] [Crossref]
200. Toteu, S.F., Penaye, J., Djomani, Y.P. (2004). Geodynamic evolution of the Pan-African belt in central Africa with special reference to Cameroon. Canadian Journal of Earth Sciences. 41(1), 73-85. [Google Scholar] [Crossref]
201. USEPA. (2013). Toxicity Relationship Analysis Program (TRAP) version 1.22 United States Environmental Protection Agency, . Washington D.C., USA.: Division. Mid-Continent Ecology. [Google Scholar] [Crossref]
202. Van-Schmus, W.R., Oliveira, E.P., Da-Silva-Filho, A.F., Toteu, S.F., Penaye, J., Guimarães, I.P. (2008). Proterozoic links between the Borborema province, NE Brazil, and the central African fold belt. Geological Society, London, Special Publication. 294(1), 69-99. [Google Scholar] [Crossref]
203. Varol, M. (2011). Assessment of heavy metal contamination in sediments of the Tigris River (Turkey) using pollution indices and multivariate statistical techniques. Journal of Hazardous Materials. 195, 355–364. [Google Scholar] [Crossref]
204. Wang, X., Sun, Y., Li, S., Wang, H., (2019). Spatial distribution and ecological risk assessment of heavy metals in soil from the Raoyanghe Wetland, China. PLoS ONE , 14(8), e0220409. [Google Scholar] [Crossref]
205. Weihua, G., Liu, X., Liu, Z., Li, G., (2010). Pollution and Potential Ecological Risk Evaluation of Heavy Metals in the Sediments around Dongjiang Harbor, Tianjin. Procedia Environmental Sciences. 2, 729–736. [Google Scholar] [Crossref]
206. WHO. (1996.). Trace Elements in Human Nutrition and Health. Geneva, Switzerland. ISBN-13: 9241561734, 361. [Google Scholar] [Crossref]
207. Wu, J., West, L. J., Stewart, D.I., (2002). Effect of humic substances on Cu (II) solubility in kaolin-sand soil. Journal of Hazardous Materials. 94(3), 223-238. [Google Scholar] [Crossref]
208. Guan, Y., Shao, C., Ju, M., (2014). Heavy metal contamination assessment and partition for industrial and mining gathering areas. International journal of environmental research and public health. 11(7), 7286-7303. [Google Scholar] [Crossref]
209. Yu, L., Cheng, J., Zhan, J., Jiang, A., (2016). Environmental quality and sources of heavy metals in the topsoil based on multivariate statistical analyses: a case study in Laiwu City, Shandong Province, China. Natural Hazards. 81(3), 1435-1445. [Google Scholar] [Crossref]
210. Zhang, X., Zhou, T.F., Yang, X.F., Yin, H.Q., Xiao, Z.H., (2005). Study on assessment methods of heavy metal pollution in river sediments. J. Hefei Univ. Technol. 28, 1419-1423. [Google Scholar] [Crossref]
211. Zhao, Q., Qi-xin, X. U., Kai, Y., (2005). Application of Potential Ecological Risk Index in Soil Pollution of Typical Polluting Industries. Journal of Eastchina Normal University (Natural Science). 1, 110-115. [Google Scholar] [Crossref]
212. Zhou, J., Dang, Z., Cai, M., Liu, C., (2007). Soil heavy metal pollution around the Dabaoshan mine,China. International Journal of Environmental Research and Public Health. 588–594. [Google Scholar] [Crossref]
Metrics
Views & Downloads
Similar Articles
- Methane Emissions from Municipal Solid Waste - Case Study in Cai Rang District, Can Tho City, Vietnam
- Youth Activism, Intentional Integration of Policies to Raise Awareness on Climate Change Action among the Youth
- Breathing Spaces: Environmental & User Experience in Dhanmondi and Zigatola Multistoried Apartments, Dhaka, Bangladesh
- Effects of Solid Waste Disposal on Soil Quality in Makurdi Metropolis, Benue State, Nigeria
- Environmental Impact of Artisanal and Small-Scale Gold Mining in Borgu Local Government Area