Rare Earth Elements as Indicators of Paleoclimate, Chemical Weathering and Redox Variability in Chodha Lake Core Sediments, Korba Region, Central India

Authors

Pranit B. Gajbhiye

P.G. Department of Geology, Rashtrasant Tukadoji Maharaj Nagpur University, Nagpur (India)

Sumedh K. Humane

P.G. Department of Geology, Rashtrasant Tukadoji Maharaj Nagpur University, Nagpur (India)

Samaya S. Humane

P.G. Department of Geology, Rashtrasant Tukadoji Maharaj Nagpur University, Nagpur (India)

Article Information

DOI: 10.51244/IJRSI.2026.1309000023

Subject Category: GEOSCIENCE

Volume/Issue: 13/9 | Page No: 267-277

Publication Timeline

Submitted: 2026-09-15

Accepted: 2026-09-20

Published: 2026-09-30

Abstract

This study presents a rare earth element geochemical record using the 48cm long sediment core recovered from the Chodha Lake of the Korba district, Chhattisgarh. The rare earth elements were used to observe the fluctuating environmental conditions in and around the study area. The core was divided into four sections based on the variability in their concentration. The entire study is based on the down core characteristics such as ΣREEs, ΣLREEs, ΣHREEs, the ΣLREEs/ΣHREEs ratio, and Ce and Eu anomalies. At most of the depths δCe values remained predominantly positive, ΣREEs, ΣLREEs, ΣHREEs and the ΣLREEs/ΣHREEs ratio were persistently low. Together, these proxies indicate dominantly oxygenated bottom water conditions and warm, humid climate governed mainly by chemical weathering leading to deposition of coarser sediments. Two notable episodic events at the depths of 26 cm in the zone-B and 17cm in the zone-C, marked by a sharp drop in δCe, increased ΣREEs and the LREE/HREE ratio indicating a brief shift to anoxic, arid/cool conditions which also led to deposition of fine sediments in the catchment. These results demonstrate that REE geochemistry provides a sensitive, internally consistent multi proxy tool for reconstructing redox and climatic fluctuations in lacustrine sedimentary archives.

Keywords

Rare Earth Elements, Environmental Conditions, Episodic Events, Sedimentary Archives, Chodha Lake

Downloads

References

1. Abou El-Anwar, E. A. (2025). Geochemical evaluation of the rare earth and trace elements in the Upper Eocene carbonate of Abu Rimth Formation, Southern Galala Plateau, Eastern Desert, Egypt. Journal of Umm Al-Qura University for Applied Sciences. https://doi.org/10.1007/s43994-025-00228-3 [Google Scholar] [Crossref]

2. Anenburg, M., & Williams, M. J. (2022). Quantifying the tetrad effect, shape components, and Ce–Eu–Gd anomalies in rare earth element patterns. Mathematical Geosciences, 54, 47–70. https://doi.org/10.1007/s11004-021-09959-5 [Google Scholar] [Crossref]

3. Antonina, N., Shazili, M., Yunus, K., Chuan, O. M., Yaacob, R., & Sharifah, F. N. (2013). Geochemistry of the rare earth elements (REE) distribution in Terengganu coastal waters: A study case from Redang Island marine sediment. Open Journal of Marine Science, 3, 154–159. https://doi.org/10.4236/ojms.2013.33017 [Google Scholar] [Crossref]

4. Bhat, N. A., Singh, B. P., Bhat, A. A., et al. (2019). Application of geochemical mapping in unraveling paleoweathering and provenance of Karewa deposits of South Kashmir, NW Himalaya, India. Journal of the Geological Society of India, 93, 68–74. https://doi.org/10.1007/s12594-019-1124-x [Google Scholar] [Crossref]

5. Condie, K. C., Dengate, J., & Cullers, R. L. (1995). Behavior of rare earth elements in a paleoweathering profile on granodiorite in the Front Range, Colorado, USA. Geochimica et Cosmochimica Acta, 59(2), 279–294. https://doi.org/10.1016/0016-7037(94)00280-Y [Google Scholar] [Crossref]

6. Domingo, J. P. T., Ngwenya, B. T., Attal, M., David, C. P. C., & Mudd, S. M. (2023). Geochemical fingerprinting to determine sediment source contribution and improve contamination assessment in mining-impacted floodplains in the Philippines. Applied Geochemistry, 159, Article 105808. https://doi.org/10.1016/j.apgeochem.2023.105808 [Google Scholar] [Crossref]

7. DRM (2005) District Resource Map of Korba District, Geological Survey of India [Google Scholar] [Crossref]

8. Gao, L., Zhuo, H., Xu, D., Qian, B., & Gao, B. (2024). Geochemical characteristics and environmental implication of rare earth elements in sediments from the Three Gorges Reservoir, China. Science of The Total Environment, 923, Article 171289. https://doi.org/10.1016/j.scitotenv.2024.171289 [Google Scholar] [Crossref]

9. Grunsky, E. C., Drew, L. J., & Sutphin, D. M. (2009). Process recognition in multi-element soil and stream-sediment geochemical data. Applied Geochemistry, 24, 1602–1616. [Google Scholar] [Crossref]

10. He, M., et al. (2024). Rare earth elements in the upstream of Yangtze River Delta: Spatio-temporal distributions, sources and speciations. Marine Pollution Bulletin, 209, Article 117103. [Google Scholar] [Crossref]

11. Kopačková-Strnadová, V., Rapprich, V., McLemore, V., Pour, O., & Magna, T. (2021). Quantitative estimation of rare earth element abundances in compositionally distinct carbonatites: Implications for proximal remote-sensing prospection of critical elements. International Journal of Applied Earth Observation and Geoinformation, 103, Article 102423. https://doi.org/10.1016/j.jag.2021.102423 [Google Scholar] [Crossref]

12. Li, X., Liang, X., He, H., Li, J., Ma, L., Tan, W., Zhong, Y., Zhu, J., Zhou, M. F., & Dong, H. (2022). Microorganisms accelerate REE mineralization in supergene environments. Applied and Environmental Microbiology, 88(13), Article e0063222. https://doi.org/10.1128/aem.00632-22 [Google Scholar] [Crossref]

13. Liu, B., & Zhao, Y. (2026). Vertical distribution characteristics of rare earth elements in sediments of the Sanjiang Plain. Scientific Reports, 16, Article 22847. https://doi.org/10.1038/s41598-026-53822-8 [Google Scholar] [Crossref]

14. Liu, H., Guo, H., Pourret, O., Wang, Z., Sun, Z., Zhang, W., & Liu, M. (2021). Distribution of rare earth elements in sediments of the North China Plain: A probe of sedimentation process. Applied Geochemistry, 134, Article 105089. https://doi.org/10.1016/j.apgeochem.2021.105089 [Google Scholar] [Crossref]

15. Maulana, A., Yonezu, K., & Watanabe, K. (2014). Geochemistry of rare earth elements (REE) in the weathered crusts from the granitic rocks in Sulawesi Island, Indonesia. Journal of Earth Science, 25(3), 460–472. https://doi.org/10.1007/s12583-014-0449-z [Google Scholar] [Crossref]

16. Mir, I., Mascarenhas-Pereira, M., & Khare, N. (2022). Geochemistry and granulometry as indicators of paleoclimate, weathering, and provenance of sediments for the past 1,00,000 years in the eastern Arabian Sea. Journal of Asian Earth Sciences, 227, Article 105102. https://doi.org/10.1016/j.jseaes.2022.105102 [Google Scholar] [Crossref]

17. Phani, P. R. C., & Sengupta, P. (2026). Geochemical studies and economic perspective of light rare earth element (LREE) enriched carbonatite from Khaderpet, Eastern Dharwar Craton. Discover Geosciences, 4, Article 308. https://doi.org/10.1007/s44288-026-00663-7 [Google Scholar] [Crossref]

18. Sandeep, K., Shankar, R., & Warrier, A. (2022). A Late Holocene record of variations in the chemical weathering intensity and pedogenesis in a lake catchment from Southern India. Aquatic Geochemistry, 28, 1–16. https://doi.org/10.1007/s10498-021-09402-5 [Google Scholar] [Crossref]

19. Sousa, T. A., Venancio, I. M., Marques, E. D., Figueiredo, T. S., Nascimento, R. A., Smoak, J. M., Albuquerque, A. L. S., Valeriano, C. M., & Silva-Filho, E. V. (2022). REE anomalies changes in bottom sediments applied in the western equatorial Atlantic since the Last Interglacial. Frontiers in Marine Science. https://doi.org/10.3389/fmars.2022.846976 [Google Scholar] [Crossref]

20. Strakhovenko, V., Belkina, N., Subetto, D., Rybalko, A., Efremenko, N., Kulik, N., Potakhin, M., Zobkov, M., Ovdina, E., & Ludikova, A. (2023). Distribution of rare earth elements and yttrium in water, suspended matter and bottom sediments in Lake Onego: Evidence of the watershed transformation in the Late Pleistocene. Quaternary International, 644–645, 120–133. https://doi.org/10.1016/j.quaint.2021.07.011 [Google Scholar] [Crossref]

21. Taylor, S. R., & McLennan, S. M. (1995). The geochemical evolution of the continental crust. Reviews of Geophysics, 33(2), 293–301. https://doi.org/10.1029/95RG00262 [Google Scholar] [Crossref]

22. Taylor, S. R., & McLennan, S. M. (1985). The continental crust: Its composition and evolution. Blackwell Scientific. [Google Scholar] [Crossref]

23. Tostevin, R., Shields, G. A., Tarbuck, G. M., He, T., Clarkson, M. O., & Wood, R. A. (2016). Effective use of cerium anomalies as a redox proxy in carbonate-dominated marine settings. Chemical Geology, 438, 146–162. https://doi.org/10.1016/j.chemgeo.2016.06.027 [Google Scholar] [Crossref]

24. Umrao, R. K., & Sardar, S. K. (2022). Significant occurrences of REE in Tertiary sequence of East Jaintia Hills, Meghalaya, India. Journal of the Geological Society of India, 98, 621–626. https://doi.org/10.1007/s12594-022-2036-8 [Google Scholar] [Crossref]

25. Wang, S., Wang, Z., Gao, S., Zhang, X., Zeng, J., & Wu, Q. (2024). Rare earth elements in lake sediments record historic environmental influences from anthropogenic activities. Ecological Indicators, 159, Article 111680. https://doi.org/10.1016/j.ecolind.2024.111680 [Google Scholar] [Crossref]

26. Wang, Y.-L., Liu, Y.-G., & Schmitt, R. A. (1986). Rare earth element geochemistry of South Atlantic deep-sea sediments: Ce anomaly change at ~54 My. Geochimica et Cosmochimica Acta, 50(7), 1337–1355. https://doi.org/10.1016/0016-7037(86)90310-8 [Google Scholar] [Crossref]

27. Wright-Clark, J., & Holser, W. T. (1981). Rare-earth elements in conodont apatite as a measure of redox conditions in ancient seas. Geological Society of America Bulletin, 13, 586. [Google Scholar] [Crossref]

28. Wu, X., Gu, C., & Probst, A. (2026). Geochemical associations and local prediction of rare earth elements in fine-grained stream and pond sediments from agricultural catchments (SW France). Applied Geochemistry, 206, Article 106909. https://doi.org/10.1016/j.apgeochem.2026.106909 [Google Scholar] [Crossref]

29. Xia, Z., Zhang, J., Wu, N., He, M., Liu, Q., & Zhao, Z. (2025). Behavior of rare earth elements during the chemical weathering of two granite profiles in different climatic regions of southern China. Applied Geochemistry, 181, Article 106303. https://doi.org/10.1016/j.apgeochem.2025.106303 [Google Scholar] [Crossref]

30. Xu, F., Li, A., Li, T., Xu, K., Chen, S., Qiu, L., et al. (2011). Rare earth element geochemistry in the inner shelf of the East China Sea and its implication to sediment provenances. Journal of Rare Earths, 29(7), 702–709. https://doi.org/10.1016/s1002-0721(10)60526-1 [Google Scholar] [Crossref]

Metrics

Views & Downloads

Similar Articles