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Synthesis of Derivatives of Heterobimetallic [Sn(II);Ti(IV)]-µ-oxo-isopropoxide with Schiff Bases

Authors

Jashmer Singh

DAV College (Lahore) Ambala City-134003, Haryana (India)

Article Information

DOI: 10.51244/IJRSI.2025.1210000195

Subject Category: Chemistry

Volume/Issue: 12/10 | Page No: 2197-2202

Publication Timeline

Submitted: 2025-11-02

Accepted: 2025-11-08

Published: 2025-11-15

Abstract

With an aim to enhance the stability and volatility of the heterometallic [Sn(II);Ti(IV)]-µ-oxo-isopropoxide a number of substitution reactions of the complex are carried out with different schiff bases viz Salicylidene aniline (HSB1), Salicylidene-o-toluidene (HSB2) and Salicylidene-p-chloroaniline (HSB3) have been performed in different molar ratios in refluxing benzene resulting in to the formation of products of the type [SnO2Ti2(O-i-Pr)5(SB)], [SnO2Ti2(O-i-Pr)4(SB)2], [SnO2Ti2(O-i-Pr)3(SB)3] and [SnO2Ti2(O-i-Pr)2(SB)4]. The schiff base derivatives have been characterized by elemental, liberated isopropanol and spectral analysis (IR, 1H , 13C NMR).

Keywords

Metal alkoxide, schiff base, Tin

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